Journal
JOURNAL OF CATALYSIS
Volume 269, Issue 1, Pages 93-102Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2009.10.020
Keywords
Heterogeneous catalysis; Rhodium; Molybdenum; Bimetallic; Organometallic precursors; Hydrogenation; Amide; Primary amine; Selectivity; Characterization
Categories
Funding
- EPSRC
- Daresbury [GR/S14252/01]
- Leverhulme Fine Chemicals Forum
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Rh/Mo catalysts formed in situ from Rh-6(CO)(16) and MO(CO)(6) are effective for the liquid phase hydrogenation of CyCONH2 to CyCH2NH2 in up to 87% selectivity, without the requirement for ammonia to inhibit secondary amine formation. Use of in situ HP-FTIR spectroscopy has shown that decomposition of metal carbonyl precursors occurs during an extended induction period, with the generation of recyclable, heterogeneous, bimetallic catalysts. Variations in Mo:Rh content have revealed significant synergistic effects on catalysis, with optimum performance at values of ca. 0.6, and substantially reduced selectivities at >= 1. Good amide conversions are noted within the reaction condition regimes 50-100 bar H-2 and 130-160 degrees C. Ex situ characterization of the catalysts, using XRD, XPS and EDX-STEM, has provided evidence for intimately mixed (ca. 2-4 nm) particles that contain metallic Rh and reduced Mo oxides, together with MoO3. Silica-supported Rh/Mo analogues, although active, perform poorly at < 150 degrees C and deactivate during recycle. (c) 2009 Elsevier Inc. All rights reserved.
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