Journal
JOURNAL OF CATALYSIS
Volume 260, Issue 1, Pages 1-6Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2008.08.012
Keywords
Amine; Gold; Heterogeneous catalysis; Imine; Oxidation; Oxygen
Categories
Funding
- U.S. Department of Energy [DE-AC02-07CH11358]
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Both bulk gold powder (similar to 50 mu m particle size) and alumina-supported gold (50-150 nm) are highly active catalysts for the aerobic oxidative dehydrogenation of amines (CH-NH) to imines (C=N) under the mild conditions of 1 atm O-2 and 100 degrees C. Reactions using the 5% Au/Al2O3 catalyst make efficient use of the gold metal and offer a practical synthesis of imines from amines. These studies add to the growing list of reactions that are catalyzed by bulk gold metal. (C) 2008 Elsevier Inc. All rights reserved.
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