4.0 Article

Formation of C-Glycosides by Ferrier Reaction

Journal

JOURNAL OF CARBOHYDRATE CHEMISTRY
Volume 32, Issue 8-9, Pages 502-512

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/07328303.2013.860160

Keywords

Glycals; C-Glycosylation; Alkyne nucleophiles; Allylic rearrangement

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Peracetylated glycals were treated with terminal alkyne derivatives under Lewis acid catalysis to result in the formation of the pure - or - anomerically substituted hex-2-enopyranosides carrying 2(E)-halogenated olefins.

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