Journal
JOURNAL OF CARBOHYDRATE CHEMISTRY
Volume 30, Issue 7-9, Pages 618-625Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/07328303.2011.618895
Keywords
X-ray crystal structure; Fluorinated carbohydrate; Structure
Funding
- European Community [4061]
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The crystal structure of a reducing dibenzylated tetrafluorinated galactose derivative is reported. The compound crystallized as the alpha-anomer, and a single OH center dot center dot center dot O hydrogen bond dominates the crystal packing, leading to a helical arrangement containing two galactose derivatives per turn. Interestingly, the helices are cross-linked by ArC-H center dot center dot center dot F contacts, but without significant Ar-Ar interactions.
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