Numerical Simulation of In-Situ Combustion Experiments Operated Under Low Temperature Conditions

During in-situ combustion (ISC) processes, different chemical reactions occur depending on the temperature level. In heavy oils and bitumens, low temperature oxidation (LTO) reactions dominate below 300 degrees C, increasing the density and viscosity and producing coke which could prevent the success of ISC. Above 350 degrees C, combustion reactions dominate, known as high temperature oxidation (HTO), producing carbon oxides and water. Numerical models tend to include only thermal cracking and HTO reactions, as LTO reactions are not well understood. In the present work, ISC experiments operated under LTO were simulated, using Saturates, Aromatics, Resins and Asphaltenes (SARA) fractions to characterize the Athabasca bitumen. Concentration profiles and coke deposition for individual temperatures were matched for isothermal experiments from 60 degrees C to 150 degrees C. Based on these results, ramped temperature oxidation (RTO) experiments were then modelled, incorporating the heat of reaction at LTO. Different reaction models were studied to match temperature profiles along the reactor, oxygen consumption, coke formation and fluids production. This research will greatly increase the understanding of LTO reactions occurring in Athabasca bitumen during ISC and contribute to the creation of a reliable numerical model that predicts ISC performance under ideal (HTO) and, importantly, non-ideal (LTO) temperature conditions.