The Shanggong gold deposit, Eastern Qinling Orogen, China: Isotope geochemistry and implications for ore genesis

The Shanggong Au deposit in the Xiong'er Terrane, East Qinling, China, has resources of about 30 ton Au, making it one of the largest orogenic-mesothermal Au deposits hosted in volcanic rocks of the Mesoproterozoic Xiong'er Group. Three stages of hydrothermal activity are recognized (early, middle and late), of which two (early and middle) were ore producing and characterized by quartz-pyrite and polymetallic sulfides, respectively. The third and late stage is represented by a carbonate-quartz assemblage. Hydrogen, oxygen and carbon isotope systematics of the Shanggong deposit from a previous work suggest that the early stage fluids were derived from magmatic and/or metamorphic devolatilization of sedimentary rocks at depth. This is supported by new C, S and published Sr and Pb isotopic data, presented in this paper. These new data, delta C-13 values ranging from 1.5 parts per thousand for early stage ankerite to -2,2 parts per thousand for late stage ankerite, negative delta S-34 values for sulfides from the middle stage (-19.2 to -6.3 parts per thousand), suggest a contribution from organic matter and that the ore fluid evolved from deeply sourced to shallowly sourced, with those of the middle stage representing a mixture of these two fluid systems. The comparison of the hydrogen-oxygen-carbon-sulfur-lead-strontium isotope systematics between the Shanggong deposit and the main lithologies in the Xiong'er Terrane, shows that neither these nor the underlying lower crust and mantle, or combinations thereof, could be considered as the source of ore fluids for the Shanggong Au deposit. A likely source was a carbonaceous carbonate, sandstone, shale, chert sequence in the underthrusted Guandaokou and Luanchuan Groups, exposed south of the Xiong'er Terrane. Ar-Ar and Rb-Sr isochron ages for mineral phases of the early, middle and late stages, together with geological field data, constrain the timing of the hydrothermal activity and Au metallogenesis at 242 +/- 10, 167 +/- 7 and 112 +/- 7 Ma, respectively. This metallogenesis and associated granitic magmatism, can be related to the continental collision between the Yangtze and North China Cratons that resulted in the formation of the Qinling Orogen, led to the different hydrothermal systems that were responsible for the three stages that formed the Shanggong Au deposit, over a period of about 130 Myrs. (c) 2008 Elsevier Ltd. All rights reserved.