Geochemical characterization of ochre from central coastal British Columbia, Canada

The use of ochre and its presence in archaeological contexts is well documented archaeologically, ethnographically and historically. Elemental analysis of ochre is becoming increasingly common as a method for identifying ancient quarrying and mining practices, and for identifying patterns of resource use, trade and exchange. As this type of work has become more common it has become apparent that two critical issues need to be considered: (1) the need for systematic identification of trends and patterns in ochre geochemistry using appropriate statistical analyses, and, (2) consideration of geographic and geologic scale in relation to ochre chemistry. Because ochre is a heterogeneous material relative to other raw material types, it is necessary to apply multivariate and discriminant statistics to differentiate geochemical groups within a sample set. However, caution must be taken when interpreting statistical results at face value. Local geologic and geomorphologic conditions play a significant role in ochre chemistry and need to be taken into account when interpreting analytical results. The purpose of this project was to determine if geochemically distinct groups of ochre could be distinguished through neutron activation analysis (NAA) of archaeological and geological ochres from the central coast of British Columbia, Canada. The results show that it is possible to satisfy the provenance postulate and to differentiate chemical groups through elemental characterization and using multivariate statistical methods. (C) 2011 Elsevier Ltd. All rights reserved.