Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 132, Issue 1, Pages -Publisher
WILEY-BLACKWELL
DOI: 10.1002/app.41230
Keywords
coatings; films; morphology; surfaces and interfaces
Categories
Funding
- Basic Science Research Program through the National Research Foundation (NRF) of Korea - Ministry of Science, ICT & Future Planning of Korea [2013-026989]
- Mid-career Research Program through the National Research Foundation (NRF) of Korea - Ministry of Science, ICT & Future Planning of Korea [2010-0015063, 2012-047815]
- NRF fund [2009-0093817]
- National Research Foundation of Korea [2009-0093817] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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We demonstrated a facile route to the preparation of self-assembled poly(vinylidene fluoride-co-trifluoroethylene) [P(VDF-TrFE)] nanodots from spin-coated thin films. We found that the initial film thickness would play an important role in the formation of such P(VDF-TrFE) nanodots. Interestingly, the electric dipoles of such nanodots were self-aligned toward the bottom electrode and their ferroelectric properties were determined by using piezoresponse force microscopy. In addition, the self-polarized ferroelectric nanostructures were introduced to small molecular organic photovoltaic devices and allowed for enhancing the short circuit current density (J(sc)) from 9.4 mA/cm(2) to 10.2 mA/cm(2) and the power conversion efficiency from 2.37% to 2.65%. (C) 2014 Wiley Periodicals, Inc.
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