Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 131, Issue 7, Pages -Publisher
WILEY
DOI: 10.1002/app.40068
Keywords
foams; rheology; mechanical properties; viscosity and viscoelasticity; thermal properties
Categories
Funding
- National Nature Science Foundation of China [51273183, 51173174]
- Founder's Foundation of Institute of Chemical Materials, China Academy of Engineering Physics [626010943]
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A series of highly thermostable epoxy foams with diglycidyl ether of bisphenol-A and bisphenol-S epoxy resin (DGEBA/DGEBS), 4,4-diaminodiphenyl sulfone (DDS) as curing agent have been successfully prepared through a two-step process. Dynamic and steady shear rheological measurements of the DGEBA/DGEBS/DDS reacting mixture are performed. The results indicate all samples present an extremely rapid increase in viscosities after a critical time. The gel time measured by the crossover of tan is independent of frequency. The influence of SiO2 content on morphology, thermal, and mechanical properties of epoxy foams has also been investigated. Due to the heterogeneous nucleation of SiO2, the pore morphology with a bimodal size distribution is observed when the content of SiO2 is above 5 wt %. Dynamic mechanical analysis (DMA) reveals that pure epoxy foam possesses a high glass transition temperature (206 degrees C). The maximum of specific compressive strength can be up to 0.0253 MPa m(3) kg(-1) at around 1.0 wt % SiO2. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40068.
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