Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 129, Issue 5, Pages 2472-2478Publisher
WILEY
DOI: 10.1002/app.38891
Keywords
blends; copolymers; grafting; membranes; poly(vinyl chloride)
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Funding
- Natural Science Foundation of Fujian Province [2011J01044]
- Scientific Research Foundation in Fuzhou University [2010-XQ-17, 022284]
- Opening Research Foundation of Key Laboratory of Biomedical Material in Tianjin City [00801103]
- Scientific Major Research Project of Fujian Province in China [2010NZ0001-1]
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In this study, a comblike amphiphilic graft copolymer containing poly(vinyl chloride) (PVC) backbones and poly(oxyethylene methacrylate) [poly(ethylene glycol) methylether methacrylate (PEGMA)] side chains was facilely synthesized via an atom transfer radical polymerization method. Secondary chlorines in PVC were used as initial sites to graft a poly[poly(ethylene glycol) methylether methacrylate] [P(PEGMA)] brush. The synthesized PVC-g-P(PEGMA) graft copolymer served as an efficient additive for the hydrophilicity modification of the poly(vinylidene fluoride) (PVDF) membrane via a nonsolvent-induced phase-inversion technique. A larger pore size, higher porosity, and better connectivity were obtained for the modified PVDF membrane; this facilitated the permeability compared to the corresponding virgin PVDF membrane. In addition, the modified PVDF membrane showed a distinctively enhanced hydrophilicity and antifouling resistance, as suggested by the contact angle measurement and flux of bovine serum albumin solution tests, respectively. Accordingly, the PVC-g-P(PEGMA) graft copolymer was demonstrated as a successful additive for the hydrophilicity modification, and this study will likely open up new possibilities for the development of efficient amphiphilic PVC-based copolymers for the excellent hydrophilicity modification of PVDF membranes. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
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