Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 130, Issue 4, Pages 2796-2800Publisher
WILEY-BLACKWELL
DOI: 10.1002/app.39488
Keywords
nanotubes; graphene and fullerenes; polystyrene; self-assembly
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Funding
- Department of Energy [DE/FG36-06GO86072]
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Polymer tethered C-60 fullerenes (PTFs) were synthesized by reacting amine terminated polystyrenes with fullerene under ambient conditions. While toluene was employed as the primary solvent in the synthesis, polar co-solvents were incorporated in various ratios to determine their effect on the reaction yield and nature of the product. The resultant PTFs were analyzed by GPC and UV-Vis spectroscopy to determine the number of adducts. The addition of a polar co-solvent was found to significantly affect the reaction rate, yield, and total number of substitutions on the fullerene. (c) 2013 Wiley Periodicals, Inc.
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