Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 125, Issue 5, Pages 3617-3629Publisher
WILEY
DOI: 10.1002/app.36522
Keywords
complex-formation; structure-property relations; monomer reactivity ratios; radical polymerization; thermal properties
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Funding
- Scientific and Technological Research Council of Turkey (TUBITAK) [TBAG-106T141]
- Hacettepe University Scientific Research Foundation [BAB-05D11601003]
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Novel functional temperature-sensitive amphiphilic P-containing polymers were synthesized by complex-radical ternary polymerization of vinylphosphonic acid (VPA), styrene (S), and maleic anhydride (MA). Charge transfer complexes (CTCs), complex-formation constants (Kc) between acceptor and donor monomer systems and the complexed monomer reactivity ratios were investigated by 1H-NMR analysis. Contrary to theoretical predictions, the VPA.S complex is more active as compared to MA.S complex in the ternary system since VPA monomer can form the CTC both with S monomer and strong H-bonded complex with MA monomer. The terpolymer compositions, characterizations, and structureproperty relationships of a series of poly(VPA-co-S-co-MA)s were investigated by GPC, FTIR, Raman, 1H-NMR, 13C-NMR, DEPT-135, 31P-NMR, TGA-DSC, DMA, XRD, viscometry, and titration. (C) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
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