Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 111, Issue 3, Pages 1286-1292Publisher
WILEY
DOI: 10.1002/app.29166
Keywords
rheology; membrane; viscosity; modeling
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Funding
- Clare Booth Luce Foundation
- Center for Automation Technologies and Systems at Rensselaer Polytechnic institute, BASF Fuel Cell, GmbH
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The viscosity behavior of various compositions of polymer electrolyte membrane solutions, which are later hydrolyzed into proton conducting membrane film for fuel cells, is characterized. Using the Carreau-Yasuda model and time-temperature superposition, an empirical model relating the viscosity as a function of temperature and shear strain rate has been developed for several membrane solution compositions. It is observed that the viscosity of the non-Newtonian membrane has a strong correlation to the membrane's inherent viscosity (a property determined during membrane synthesis). (c) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 1286-1292, 2009
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