Influence of fiber modification on interfacial adhesion and mechanical properties of pineapple leaf fiber-epoxy composites

Three kinds of surface treatment, that is, the alkalization (5% w/v NaOH aqueous Solution), the deposition of diglycidyl ether of bisphenol A (DGEBA) from toluene Solution (1% w/v DGEBA and the alkalization combined with the deposition of DGEBA (5% w/v NaOH/1% w/v DGEBA) were applied to modify interfacial bonding and to enhance mechanical properties of pineapple leaf fiber (PALF) reinforced epoxy composites. The fiber strength and strain were measured by single fiber test and the fiber strength variation was assessed using Weibull modulus. Furthermore, a fragmentation test was used to quantity the interfacial adhesion of PALF-epoxy composite. It was verified that the interfacial shear strength of modified PALFs was substantially higher than that Of untreated PALF by almost 2-2.7 times because of the greater interaction between the PALFs and epoxy resin matrix. The strongest interfacial adhesion was obtained from the fibers that had been received the alkalization combined with DGEBA deposition. Moreover, the flexural and impact properties of unidirectional PALF-epoxy composites were greatly enhanced when reinforced with the modified PALFs due to an improvement in interfacial adhesion, particularly in the synergetic use of 5%, NaOH and 5% NaOH/1% DGEBA. (C) 2008 Wiley Periodicals, Inc.