Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 110, Issue 6, Pages 3902-3907Publisher
JOHN WILEY & SONS INC
DOI: 10.1002/app.28865
Keywords
catalysts; polycarbonates; polycondensation
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Funding
- New, Energy and Industrial Technology Development Organization (NEDO)
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Polycarbonates (PCs) were prepared by oxidative carbonylation of bisphenol A and carbon monoxide, using a Pd-polybipylidyl complex, Pd-polyvinylpyridine complex, smectite-supported Pd complex, or hydrotalcite-supported Pd complex as a heterogeneous Pd catalyst to separate the PC solution and the Pd catalyst after the reaction. Propylene carbonate was used as a halogen-free solvent. When Co(OAc)(2)center dot H2O was used as the inorgano-redox catalyst, all of the Pd compounds gave a pod PC yield with the recycling potential of the catalyst. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110: 3902-3907,2008
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