Journal
JOURNAL OF APPLIED PHYSICS
Volume 105, Issue 5, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3079797
Keywords
aggregation; crystal orientation; diffusion; excitons; organic semiconductors; photoluminescence; radiation quenching; semiconductor thin films
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Funding
- Global Photonic Energy Corporation
- Air Force Office of Scientific Research
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We demonstrate spectrally resolved photoluminescence quenching as a means to determine the exciton diffusion length of several archetype organic semiconductors used in thin film devices. We show that aggregation and crystal orientation influence the anisotropy of the diffusion length for vacuum-deposited polycrystalline films. The measurement of the singlet diffusion lengths is found to be in agreement with diffusion by Forster transfer, whereas triplet diffusion occurs primarily via Dexter transfer.
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