4.6 Article

Self-lubricating carbon nanotube reinforced nickel matrix composites

Journal

JOURNAL OF APPLIED PHYSICS
Volume 106, Issue 1, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3158360

Keywords

Auger electron spectra; carbon nanotubes; composite materials; friction; laser materials processing; lubrication; nickel; Raman spectra; shear strength; wear

Funding

  1. U. S. Air Force Office of Scientific Research [FA955006-1-0193]
  2. American Chemical Society Petroleum Research Fund [46915-G5]

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Nickel (Ni)-multiwalled carbon nanotube (CNT) composites have been processed in a monolithic form using the laser-engineered net shape (LENS (TM)) processing technique. Auger electron spectroscopy maps determined that the nanotubes were well dispersed and bonded in the nickel matrix and no interfacial chemical reaction products were determined in the as-synthesized composites. Mechanisms of solid lubrication have been investigated by micro-Raman spectroscopy spatial mapping of the worn surfaces to determine the formation of tribochemical products. The Ni-CNT composites exhibit a self-lubricating behavior, forming an in situ, low interfacial shear strength graphitic film during sliding, resulting in a decrease in friction coefficient compared to pure Ni.

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