Journal
JOURNAL OF APPLIED PHYSICS
Volume 106, Issue 5, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.3202385
Keywords
high-pressure solid-state phase transformations; organic compounds; polymorphism; reflectivity
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Funding
- FASTSWITCH [CNCSIS-IDEI 1994]
- Agence Universitaire de la Francophonie (AUF)
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We investigated by diffuse reflectivity the effect of hydrostatic pressure (1-1800 bar) on the thermal spin transition of Fe(PM-BiA)(2)(NCS)(2) polymorph I, where PM=N-2-pyridylmethylene and BiA=4-aminobiphenyl. We evidenced the onset of a progressive transformation into a phase of higher cooperativity which cannot be assigned to polymorph II. This result is discussed with respect to previous pressure investigations.
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