4.6 Article

Nanosecond response of organic solar cells and photodetectors

Journal

JOURNAL OF APPLIED PHYSICS
Volume 105, Issue 10, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.3130399

Keywords

current density; electron mobility; hole mobility; organic compounds; photodetectors; photodiodes; SCF calculations; solar cells; space charge

Funding

  1. Deutsche Forschungsgemeinschaft (DFG)
  2. State of Baden-Wurttemberg through the DFG-Center for Functional Nanostructures (CFN)

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We examine the impact of various parameters on the transient current density characteristics of organic solar cells and photodetectors by means of numerical simulations. Our self-consistent numerical model treats the dynamics of generated electrons and holes in the framework of a drift-diffusion model. As input parameter for the electric model, the intensity distribution of the incident light is calculated with a transfer-matrix method accounting for interference effects. The results are compared to experimental results. With our approach, we are able to distinguish the influence of different physical effects as they become dominant at different current densities or at different time regimes. This enables us to estimate the electron and hole mobilities separately by fitting the experimental results. Furthermore, space charge effects are identified as being highly important for the transient response of photodetectors.

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