Journal
JOURNAL OF APPLIED PHYSICS
Volume 104, Issue 6, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2973682
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Funding
- University Grants Commission
- Nano Mission of Department of Science and Technology [SR/S5/NM-90/2006]
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An analysis is given of the electronic structure of Pd nanoparticles synthesized by inert gas evaporation technique. A study of the effect of size on various core and valence electrons in Pd nanoparticles reveals a varied dependence of binding energy of electrons in different electronic levels. The shift in the Pd x-ray photoelectron spectroscopy 4d valence band centroid is more than the core level shift. The results of the present study provide a direct evidence of interplay of quantum confinement (a size effect) and coordination reduction (a surface effect). (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2973682]
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