Journal
JOURNAL OF APPLIED PHYSICS
Volume 103, Issue 7, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2837241
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We have employed element and chemically sensitive x-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism (XMCD) in order to address a long standing controversy regarding the electronic and magnetic states of CuCr(2)Se(4) via halogen doping of the Se anion site in CuCr(2)Se(4-x)Y(x) (Y=Cl and Br). Long range magnetic order is observed above room temperature for all samples. The Cr L(2,3) XAS spectra show a prevalent 3+ valence for the Cr ions independent of doping concentration and doping agent. The Cu L(2,3) XAS spectra show a combination of 1+ and 2+ valence states for all samples. XMCD spectra indicate the presence of a magnetic moment associated with the Cu ions that is aligned antiparallel to the Cr moment. (C) 2008 American Institute of Physics.
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