Journal
JOURNAL OF APPLIED ELECTROCHEMISTRY
Volume 45, Issue 3, Pages 225-233Publisher
SPRINGER
DOI: 10.1007/s10800-014-0780-1
Keywords
Lithium ion cell; LiFePO4/C; Electrode reaction; Temperature; Li+ ion diffusion coefficient
Categories
Funding
- Natural Science Foundation of Yunnan Province, PR China [2010ZC051]
- Analysis and Testing Foundation [20140439]
- Kunming University of Science and Technology, PR China [14118245]
Ask authors/readers for more resources
A LiFePO4/C sample was prepared via solid state reaction and characterized with X-ray powder diffraction, scanning electron microscopy and charge-discharge test. Conductive carbon and highly crystallized LiFePO4 were embedded in each other to form the as-prepared LiFePO4/C, which exhibited an excellent rate capability and capacity retention. The LiFePO4/C electrode reaction was investigated by the method of medium scan rate cyclic voltammetry (CV) under temperature variation. The limit values for the CV redox peak potentials of the LiFePO4/C electrode scanned at different rates were obtained by curve fitting. The reversibility of the LiFePO4/C electrode was studied and found to be both scan rate and temperature dependent. A higher temperature led to a higher critical CV scan rate for a reversible LiFePO4/C electrode. In the electrode process, a higher temperature resulted in a smoother Fe3+/Fe2+ redox reaction, better reversibility, lower R (cv), smaller charge transfer resistance and higher Li+ ion diffusion coefficient at the cathode of the LiFePO4/C.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available