Journal
JOURNAL OF APPLIED ELECTROCHEMISTRY
Volume 41, Issue 11, Pages 1295-1299Publisher
SPRINGER
DOI: 10.1007/s10800-011-0344-6
Keywords
LiMn2O4; SEI; LiF; Soft X-ray absorption spectroscopy; Lithium secondary batteries
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Funding
- National Research Foundation of Korea (NRF)
- Ministry of Education, Science, and Technology (MEST) [2010-00351]
- Office of Vehicle Technologies of the US Department of Energy [DE-AC02-98CH10886]
- National Research Laboratory through the National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology (MEST) [2007-0055835]
- Korean Government (MKE)
- National Research Foundation of Korea [2011-56529, 2010-00351, 2007-0055835] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The solid electrolyte interface (SEI) formation on the surface of LiMn2O4 electrodes during room temperature charge-discharge cycling was studied using soft X-ray absorption spectroscopy at the Fluorine (F) K-edge. LiMn2O4 electrodes without any binder were prepared by electrostatic spray deposition to eliminate the signal originating from the PVDF binder in the F K-edge X-ray absorption spectra. The F K-edge absorption spectra show that the SEI layer forms at a very early stage of cycling. SEI growth takes place during discharge. In addition, LiF formation is accelerated if the discharge step follows a charge step. The F K-edge absorption spectra suggest that the major component of the SEI is LiF.
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