Journal
JOURNAL OF APPLIED ELECTROCHEMISTRY
Volume 41, Issue 2, Pages 189-196Publisher
SPRINGER
DOI: 10.1007/s10800-010-0223-6
Keywords
Flowerlike; Co3O4 nanoparticles; Quercetin; Sensor
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Japan Science and Technology Agency (JST)
- State Natural Sciences Foundation [50873042]
- Jiangsu Marine Resource Development Research Institute Foundation [JSIMR09B05]
- Marine Key Lab Foundation of Jiangsu Province [2010HS11]
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Flowerlike Co3O4 nanoparticles were used as a modifier on the glassy carbon electrode to fabricate a quercetin (Qu) sensor. The morphology and crystallinity of the prepared Co3O4 material were investigated by scanning electron microscopy and X-ray diffraction. Electrochemical behavior of Qu at the sensor was studied by cyclic voltammetry and semi-derivative voltammetry. Results suggested that the modified electrode exhibited a strong electrocatalytic activity toward the redox of Qu. The electron transfer coefficient (alpha), the number of electron transfer (n), and the diffusion coefficient (D) of Qu at the sensor were calculated. Under the optimum conditions, the catalytic peak currents of Qu were linearly dependent on the concentrations of Qu in the range from 5.0 x 10(-7) to 3.3 x 10(-4) M, with a detection limit of 1.0 x 10(-7) M. This proposed method was successfully applied to determine the quercetin concentration in Ginkgo leaf tablet and human urine samples.
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