4.7 Article

Physicochemical and agronomic properties of biochar from sewage sludge pyrolysed at different temperatures

Journal

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
Volume 102, Issue -, Pages 124-130

Publisher

ELSEVIER
DOI: 10.1016/j.jaap.2013.03.006

Keywords

Sewage sludge; Pyrolysis; Biochar; Soil

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Biochar is a carbon-rich solid product obtained by pyrolysis of biomass. Their properties depend on the raw material characteristics and pyrolysis conditions. The main objective of present work is to study the physicochemical and agronomic properties of biochar from sewage sludge pyrolysed at two temperatures. Feedstock was obtained by co-composting of sewage sludge with pruning waste in a treatment plant in Madrid region (Spain). Biochar was prepared at 400 degrees C and 600 degrees C leading to samples referenced CAP-400 and CAP-600, respectively. pH, BET surface area, porosity and total concentration of Cu, Ni, Zn, Cd and Pb increases with pyrolysis, whereas electrical conductivity (EC) and cation exchange capacity (CEC) decrease, specially with treatment at 600 degrees C. So, the volatile matter of biochar decreased with the increment of pyrolysis temperature from 400 degrees C to 600 degrees C while the biochar fixed carbon was similar at two pyrolysis temperatures. These differences on biochar properties have a significant influence on their effects on soil properties. (c) 2013 Elsevier B.V. All rights reserved.

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