4.7 Article

Phenolic compound formation from the low temperature pyrolysis of tobacco

Journal

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
Volume 84, Issue 2, Pages 170-178

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jaap.2009.01.008

Keywords

Oxygen; Phenolic compounds; Pyrolysis; Tobacco

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The formation of 10 phenolic compounds (hydroquinone, resorcinol, catechol, phenol, 4-methylcatechol, 3-methylcatechol, guaiacol, o-, m-, and p-cresol) from the pyrolysis of different tobacco types at temperatures between 350 and 600 degrees C was investigated. Hydroquinone, catechol, guaiacol, 3-methylcatechol, and 4-methylcatechol were formed predominately at temperatures <= 350 degrees C from the primary decomposition of tobacco components. Cresols formed predominately between 350 and 600 degrees C and evolved from the residual solid (char) that forms at temperatures above 350 degrees C. Phenol and resorcinol were found to form over both temperature ranges, <= 350 degrees C and between 350 and 600 degrees C suggesting contributions from both the decomposition of tobacco components and the 350 degrees C residual solid. The trend in the yields of hydroquinone and catechol obtained from the tobacco types tested: bright (flue cured), burley, and oriental followed bright similar to oriental > burley. All three tobacco samples gave similar yields of phenol and cresols. Water extraction of tobacco was shown to significantly reduce the yields of phenolic compounds. The addition of 5 and 21% oxygen to the pyrolysis setup led to a significant reduction in the yields of hydroquinone and catechol but the yields of phenol and cresols remained relatively unchanged. Quinic acid and quinic acid derivatives present in tobacco are identified as important precursors of hydroquinone, catechol, and phenol. (c) 2009 Elsevier B.V. All rights reserved.

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