4.8 Article

Uniform manganese hexacyanoferrate hydrate nanocubes featuring superior performance for low-cost supercapacitors and nonenzymatic electrochemical sensors

Journal

NANOSCALE
Volume 7, Issue 38, Pages 16012-16019

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr04322k

Keywords

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Funding

  1. National Key Basic Research Program of China (973 Program) [2014CB648300]
  2. Program for graduate students research and innovation of Jiangsu Province [CXZZ12-0454]
  3. Program for New Century Excellent Talents in University [NCET-13-0645, NCET-13-0872]
  4. Program for Jiangsu Specially-Appointed Professors [RK030STP15001]
  5. National Natural Science Foundation of China [21201010, 21422402, 20904024, 51173081, 61136003, 61106036]
  6. Program for Innovative Research Team (in Science and Technology) in the University of Henan Province [14IRTSTHN004]
  7. Natural Science Foundation of Jiangsu Province [BK20140060, BK20130037, BM2012010]
  8. Synergetic Innovation Center for Organic Electronics and Information Displays, the Specialized Research Fund for the Doctoral Program of Higher Education [20133223110008]
  9. Ministry of Education of China [IRT1148]
  10. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  11. Six Talent Plan [2012XCL035]
  12. Qing Lan Project of Jiangsu Province

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Uniform manganese hexacyanoferrate hydrate nanocubes are prepared via a simple chemical precipitation method at room temperature. Due to both micro/mesopores of the Prussian blue analogue and nanocubic structures, the manganese hexacyanoferrate hydrate nanocubes allow the efficient charge transfer and mass transport for electrolyte solution and chemical species. Thus, the manganese hexacyanoferrate hydrate nanocube electrode shows a good rate capability and cycling stability for electrochemical capacitors. Furthermore, electrodes modified with manganese hexacyanoferrate hydrate nanocubes demonstrate a sensitive electrochemical response to hydrogen peroxide (H2O2) in buffer solutions with a high selectivity.

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