Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 593, Issue -, Pages 97-102Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2014.01.031
Keywords
BNT-BT-BZ; Dielectric; Ferroelectric; Piezoelectric; Field-induced strain
Categories
Funding
- National Research Foundation of Korea (NRF) [2013H1B8A2032206]
- Ministry of Education, Science and Technology (MEST) [2011-0030058]
- Ministry of Education (MOE)
- National Research Foundation of Korea [2013H1B8A2032206] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Lead-free (0.935-x)[Bi0.5Na0.5TiO3-0.065BaTiO(3)]-xBaZrO(3) (BNBT-xBZ, with x = 0-0.07) ceramics were prepared by a conventional solid-state reaction method. The effect of BZ addition on the crystal structure, microstructure, dielectric, ferroelectric and electric field induced strain behavior of BNBT ceramic was investigated. X-ray diffraction patterns of BNBT-xBZ ceramics revealed the formation of single phase perovskite structure in the studied composition range. Addition of BZ in BNBT transform the crystal structure from tetragonal to pseudocubic symmetry. However, with increasing BZ content, the maximum dielectric constant decreased and the dielectric maximum temperature (T-m) shifted towards lower temperature. The field induced strain response of BNBT-xBZ increases from 0.16% for x = 0 to 0.38% for x = 0.03, at an applied field of 7 kV/mm. The corresponding dynamic piezoelectric coefficient for these composition were (S-max/E-max = 231 pm/V) and (S-max/E-max = 542 pm/V), respectively. These results suggest that the BNBT-0.03BZ ceramic can be considered as a promising candidate material for piezoelectric application. (C) 2014 Elsevier B.V. All rights reserved.
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