Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 587, Issue -, Pages 349-353Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2013.09.151
Keywords
Titanium ions; Equilibrium constant; LiCl-KCl melts
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Funding
- National Science Foundation of China [50934001]
- National High Technology Research and Development Program of China (863 Program) [2012AA062302]
- Program of the Co-Construction with Beijing Municipal Commission of Education of China [00012047, 00012085]
- Program for New Century Excellent Talents in University [NCET-11-0577]
- Fundamental Research Funds for the Central Universities [FRF-AS-11-003A]
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The equilibrium between metallic titanium and titanium ions (Ti2+, Ti3+) dissolved in LiCl-KCl melts and the influence of the electrolyte composition on the equilibrium were investigated. The accurate concentrations of titanium ions had been obtained based on a reliable approach for taking samples. Furthermore, accurate values of the equilibrium constants were calculated by the best-fitting method under the consideration of the TiOCl dissolution. The influence of the electrolyte composition on the equilibrium was evaluated by determining the equilibrium constant K-c between titanium metal and titanium ions in LiCl-KCl melts with different concentration of LiCl. It was shown that LiCl could affect the equilibrium and the K-c values decreased with the increase of concentration of LiCl. (C) 2013 Elsevier B.V. All rights reserved.
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