Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 578, Issue -, Pages 613-619Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2013.07.036
Keywords
Thin films; Semiconductors; Chemical synthesis; Crystal structure; Optical properties; Photoelectron spectroscopies
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Undoped and Bi doped zinc oxide thin films were deposited on glass substrate at 450 degrees C using spray pyrolysis technique. The X-ray diffraction studies shows that Bi doped ZnO films are polycrystalline hexagonal structure with a preferred orientation along (1 0 1) direction. Crystallites size of the films decreases with increasing doping concentration. Scanning electron microscope image shows change in the surface morphology. The composition of Zn, O and Bi elements in the undoped and Bi doped ZnO films were investigated by X-ray photoelectron spectroscopy. Bi doped ZnO thin films show a transparency nearly 75% in the visible region. The optical band gap of ZnO thin films reduces from 3.25 eV to 3.12 eV with an increase in Bi concentration from 0 to 5 at.% respectively. Electrical conductivity of ZnO thin films increased from 0.156 to 6.02 S/cm with increasing Bi dopant concentration from 0% to 5% respectively. (c) 2013 Elsevier B.V. All rights reserved.
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