Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 515, Issue -, Pages 119-122Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2011.11.115
Keywords
KRbAl2B2O7; Solid solution; Crystal structure; NLO properties
Categories
Funding
- SB RAS [34]
- RFBR [11-02-90706-mob_st, 11-03-00867a]
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The structures of K2(1-x)Rb2xAl2B2O7, x = 0.25, 0.5, 0.75, have been determined in space group P321 through Rietveld analysis of X-ray powder diffraction data. The solubility limit in K2(1-x)Rb2xAl2B2O7 crystals has been estimated as x similar to 0.83-0.9. Nonlinear optical properties of KRbAl2B2O7 have been verified by powder Kurtz-Perry method. Mechanisms of structural parameter variation in K2Al2B2O7 crystal family have been discussed. (C) 2011 Elsevier B. V. All rights reserved.
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