4.8 Article

Self-doped Ti3+-TiO2 as a photocatalyst for the reduction of CO2 into a hydrocarbon fuel under visible light irradiation

Journal

NANOSCALE
Volume 7, Issue 32, Pages 13369-13372

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr02974k

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Funding

  1. National Science Foundation [CHE-1213795]

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Self-doped TiO2 shows visible light photocatalytic activity, while commercial TiO2 (P25) is only UV responsive. The incorporation of Ti3+ into TiO2 structures narrows the band gap (2.90 eV), leading to significantly increased photocatalytic activity for the reduction of CO2 into a renewable hydrocarbon fuel (CH4) in the presence of water vapour under visible light irradiation.

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