Journal
NANOSCALE
Volume 7, Issue 33, Pages 13836-13839Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr03688g
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Funding
- European Commission through projects ITN iSwitch [642196]
- European Research Council projects SUPRAFUNCTION [GA-257305]
- PLASMHACAT [GA-280064]
- EC-FP7-NMP-2012-SMALL-6 SACS project [GA-310651]
- Agence Nationale de la Recherche through LabEx project Chemistry of Complex Systems [ANR-10-LABX-0026_CSC]
- International Center for Frontier Research in Chemistry (icFRC)
- Swiss Nationals Science Foundation (SNF)
- Swiss Nanoscience Institute (SNI)
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pi-pi Intermolecular interactions among adjacent conjugated azobenzenes chemisorbed on (non-) flat Au surfaces can be tuned by varying the curvature of the Au nanoparticles. Here we show that such interactions rule the thermal cis-trans isomerization kinetics, towards a better control on the azobenzene bistability for its optimal integration as a responsive material.
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