Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 509, Issue 8, Pages 3553-3558Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2010.12.058
Keywords
Glass ceramics; Eu2+/Sm3+ co-doped; SrSiO3 nano-crystals; Optical properties; White LED
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Funding
- National Natural Science Foundation of China [51072190, 11004177]
- Program for New Century Excellent Talents in University [NCET-07-0786]
- Zhejiang Provincial Natural Science Foundation of China [Z4100030, Y4080268]
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Eu2+/Sm3+ co-doped silicate glass was prepared by high temperature melting under reducing atmosphere and the Eu2+/Sm3+ co-doped SrSiO3 transparent glass-ceramics were obtained after heat-treatment. X-ray diffraction (XRD) and Raman spectra confirmed the formation of SrSiO3 nano-crystals in the glass matrix. The photoluminescence excitation (PLE) spectra and photoluminescence (PL) spectra of the samples were measured. A broad emission band from 400 nm to 550 nm due to the 4f(6)d(1) -> 4f(7) transitions of Eu2+ was observed, as well as several sharp emission peaks at 563 nm, 600 nm, 646 nm and 713 nm ascribed to the 4f -> 4f transitions of Sm3+. The luminescence properties of the glass ceramics with different molar ratio of Eu2+/Sm3+ were studied and the corresponding chromaticity coordinates were calculated. The ultraviolet light-emitting diode (UV-LED) excitable glass-ceramics emitting white light were obtained by tuning the relative emission intensity of Eu2+ and Sm3+. The results indicate that the Eu2+/Sm3+ co-doped SrSiO3 transparent glass-ceramics can be used as a potential matrix material for White LED under UV-LED excitation. (c) 2010 Elsevier B.V. All rights reserved.
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