Journal
NANOSCALE
Volume 7, Issue 15, Pages 6444-6450Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr00861a
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Funding
- Industrial Strategic technology development program - Ministry of Knowledge Economy (MKE, Korea) [10041926]
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A resistive random access memory (ReRAM) based on the memristive effect allows high-density integration through a cross-point array (CPA) structure. However, a significant common drawback of the CPA configuration is the crosstalk between cells. Here, we introduce a solution based on a novel heterojunction stack solely made of members of the perovskite manganite family Pr1-xCaxMnO3 (PCMO) and CaMnO3-delta (CMO) which show electroforming-free bipolar resistive switching. The heterojunction consists of rectifying interfaces and shows a symmetrical and tunable non-linear current-voltage curve. The spectromicroscopic measurements support the scenario of specialized roles, with the memristive effect taking place at the active Al-PCMO interface via a redox mechanism, while non-linearity was achieved by adopting a rectifying double interface PCMO-CMO-PCMO.
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