4.7 Article

Synthesis, crystal structure and thermoelectric properties of the ternary skutterudite Fe2Pd2Sb12

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 493, Issue 1-2, Pages 50-54

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.12.085

Keywords

Fe2Pd2Sb12; Crystal structure; X-ray powder diffraction; Transport properties

Funding

  1. Ministry of Education of the Czech Republic [MSM0021627501]
  2. Grant Agency CR [203/07/0267]

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The Fe2Pd2Sb12 compound was synthesized and structurally characterized by powder X-ray diffraction. Fe2Pd2Sb12 has the skutterudite structure, Im (3) over bar symmetry, unit cell parameter a = 9.2048(2) angstrom, Z = 8. The transport properties of the title compound were investigated. From the temperature dependencies of electrical conductivity, the Hall coefficient and the Seebeck coefficient the existence of mixed conductivity mechanism by means of electrons and holes was proposed. (C) 2010 Elsevier BM. All rights reserved.

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