4.7 Article

The Mechanochemical synthesis of magnesium hydride nanoparticles

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 492, Issue 1-2, Pages L72-L74

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.12.006

Keywords

Hydrogen storage materials; Nanostructures; Mechanochemical synthesis; X-ray diffraction; Magnesium hydride

Funding

  1. CSIRO Energy Transformed Flagship National Hydrogen Materials Alliance (NHMA)
  2. Australia and an Australian Research Council [DP0877155]
  3. University, State and Commonwealth Governments
  4. Australian government
  5. Australian Institute of Nuclear Science and Engineering (AINSE)
  6. Australian Research Council [DP0877155] Funding Source: Australian Research Council

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A mechanochemical method was used to synthesise magnesium hydride nanoparticles with an average crystallite size of 6.7 nm. The use of a reaction buffer was employed as a means of particle size control by restricting agglomeration. Increasing the amount of reaction buffer resulted in a decrease in crystallite size, as determined via X-ray diffraction, and a decrease in particle size, evidenced by transmission electron microscopy. (C) 2009 Elsevier B.V. All rights reserved.

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