Journal
NANOSCALE
Volume 7, Issue 45, Pages 18923-18927Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr05696a
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Funding
- Korea Center for Artificial Photosynthesis [2009-0093881]
- Global Frontier R&D Program at the Center for Hybrid Interface Materials (HIM) [2013M3A6B1078884]
- National Research Foundation of Korea - Ministry of Science, ICT & Future Planning [2011-0028737, 2012M1A2A2671813]
- National Research Foundation of Korea [2011-0028737, 2009-0093881, 2013M3A6B1078884, 10Z20130011056] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Porphyrin-based isostructural porous organic networks have been synthesized by varying the central metal atoms to cobalt, nickel and copper. Their selectivities for CO2 capture over N-2 and Ar are found to be enhanced as the heats of adsorption for CO2 are increased in the order of Co, Ni and Cu, while the pore structures are well maintained.
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