Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 469, Issue 1-2, Pages 197-202Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2008.01.148
Keywords
PMMA; Thermal aging; Complex impedance; Relaxation frequency; Electrical conductivity
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Funding
- Ministere de la recherche scientifique, de la technologie et du developpement des competences, Tunisia
- ICTP through TWAS [00-043 RG/PHYS/AF/AC]
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Effects of thermal aging on electric properties of polymethyl methacrylate (PMMA) polymer are reported in this paper. PMMA samples are submitted to Successive heat-cooling cycles (T-max = 45 degrees C and T-min = 20 degrees C) in the ambient air. Different complementary techniques are thus employed to investigate structural modifications, conduction processes and dielectric relaxations. These are the Fourier Transform Infra Red (FTIR) spectroscopy, impedance spectroscopy and current-voltage technique. Results are discussed in terms of FTIR bands intensities, relaxation frequencies and electrical conductivity. We demonstrated that thermal aging favors oxidation phenomenon. This causes an increase of free radicals leading to space charge amount increasing. PMMA polymer presents therefore a less insulating character. (C) 2008 Elsevier B.V. All rights reserved.
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