Journal
NANOSCALE
Volume 7, Issue 29, Pages 12445-12451Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr02713f
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Funding
- NSFC [51373111]
- Suzhou Nano-project [ZXG2012022]
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201207]
- Academic Award for Young Graduate Scholar of Soochow University
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Due to the specific physical and chemical properties of a highly branched noble metal, the controllable synthesis has attracted much attention. This article reports the synthesis of Pd/Ru nanodendrites by a facile method using an oil bath in the presence of polyvinyl pyrrolidone, potassium bromide and ascorbic acid. The morphology, structure, and composition of the as-prepared catalysts were characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy. In the electrochemical measurement, the as-prepared Pd-7/Ru-1 bimetallic nanodendrites provide a large electrochemically active surface area and exhibit high peak current density in the forward scan toward ethanol electrooxidation, which is nearly four times higher than those of a pure Pd catalyst. The as-prepared Pd-7/Ru-1 catalysts also exhibit significantly enhanced cycling stability toward ethanol oxidation in alkaline medium, which are mainly ascribed to the synergetic effect between Pd and Ru. This indicates that the Pd-7/Ru-1 catalysts should have great potential applications in direct ethanol fuel cells.
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