Journal
NANO RESEARCH
Volume 8, Issue 8, Pages 2744-2754Publisher
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-015-0781-3
Keywords
electrodeposition; concentration-gradient; nickel cobalt hydroxides; supercapacitors
Categories
Funding
- National Natural Science Foundation of China [21001117]
- Shenzhen Peacock Plan [KQCX20140522150815065]
- South University of Science and Technology of China (SUSTC) through the Talent Plan of the Shenzhen Government
- Key Project of the Hunan Provincial Science and Technology Plan [2014FJ2007]
Ask authors/readers for more resources
Novel three-dimensional (3D) concentration-gradient Ni-Co hydroxide nanostructures (3DCGNC) have been directly grown on nickel foam by a facile stepwise electrochemical deposition method and intensively investigated as binder- and conductor-free electrode for supercapacitors. Based on a three-electrode electrochemical characterization technique, the obtained 3DCGNC electrodes demonstrated a high specific capacitance of 1,760 F center dot g(-1) and a remarkable rate capability whereby more than 62.5% capacitance was retained when the current density was raised from 1 to 100 A center dot g(-1). More importantly, asymmetric supercapacitors were assembled by using the obtained 3DCGNC as the cathode and Ketjenblack as a conventional activated carbon anode. The fabricated asymmetric supercapacitors exhibited very promising electrochemical performances with an excellent combination of high energy density of 103.0 Wh center dot kg(-1) at a power density of 3.0 kW center dot kg(-1), and excellent rate capability-energy densities of about 70.4 and 26.0 Wh center dot kg(-1) were achieved when the average power densities were increased to 26.2 and 133.4 kW center dot kg(-1), respectively. Moreover, an extremely stable cycling life with only 2.7% capacitance loss after 20,000 cycles at a current density of 5 A center dot g(-1) was achieved, which compares very well with the traditional doublelayer supercapacitors.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available