4.7 Article

Improving the Capacity of Polypropylene To Be Used in Antioxidant Active Films: Incorporation of Plasticizer and Natural Antioxidants

Journal

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
Volume 61, Issue 35, Pages 8462-8470

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jf402670a

Keywords

active packaging; antioxidant; PP; PPG-PEG-PPG; green tea; flavonoids

Funding

  1. Xunta de Galicia Government (Autonomous Community Government)
  2. FEDER: Funding for the consolidation of research University groups in Galicia

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Two types Of active antioxidant food packages With improved release properties, based on Polypropylene.(PP) as one of the most common polymers used in food packaging applications,. were developed. Incorporation of catechin and green tea as antioxidant provided PP with 6 times higher stabilization against thermal oxidation: Release of natural antioxidants (catechins, gallic acid, caffeine, and quercetin) into :various food simulants from that nonpolar matrix were improved by blending poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol) (PPG-PEG-PPG) as plasticizer into the polymer formulation. Increasing release levels between 10- and 40 fold into simulant A and between 6 and 20 fold into simulant D1 resulted, from the incorporation of catechin and green tea as antioxidants and PPG-PEG-PPG as plasticizer into the film formulation. The efficiency : Of the antioxidants in the food simulants after the release process was also corroborated through :antioxidant activity tests. Therefore, the developed PPG-PEG-PPG-modified polypropylene resulted in a potential system to be, used in active packaging.

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