4.7 Article

Urea Montmorillonite-Extruded Nanocomposites: A Novel Slow-Release Material

Journal

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
Volume 60, Issue 21, Pages 5267-5272

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jf3001229

Keywords

urea; fertilizer; montmorillonite; extrusion; intercalation

Funding

  1. CNPq
  2. CAPES
  3. FAPESP
  4. FINEP
  5. Rede Agronano-Embrapa

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The present study describes the preparation and characterization of a novel urea slow-release nanocomposite, based on urea intercalation into montmorillonite clay by an extrusion process at room temperature. Nanocomposites with urea contents ranging from 50 to 80 wt % were successfully produced and characterized. Analyses by XRD, DTA, and SEM-EDX confirmed the effectiveness of this simple process to exfoliate the clay lamellae into the urea matrix, forming a product that can be classified as a nanocomposite, due to the exfoliation degree attained. Diametral compression tests showed that the samples were very deformable, and the release rate of active components in water showed that the nanocomposite showed a slow release behavior for urea dissolution, even in low montmorillonite amounts (20% in weight).

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