Journal
JAPANESE JOURNAL OF APPLIED PHYSICS
Volume 51, Issue 10, Pages -Publisher
IOP Publishing Ltd
DOI: 10.1143/JJAP.51.10NE13
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- Core Research for Evolutional Science and Technology (CREST) of the Japan Science and Technology Agency
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We synthesized five donor-pi-spacer-acceptor type organic photosensitizers bearing different types of electron-withdrawing groups (EWGs); trifluoromethyl, o-nitrophenyl, p-nitrophenyl, cyano, and carboxyl groups, on their acceptor part in the aim of observing an influence of the EWGs on spectral and photovoltaic properties from viewpoints of steric structure and pi-conjugation. The EWG possessing smaller dihedral angle between the EWG and dye skeleton exhibited larger bathochromic shift in absorptions. Highly planer cyano group presented the most red-shifted absorption at 464 nm, and the highest conversion efficiency of 5.69% was obtained. In contrast, highly distorted o- and p-nitrophenyl groups exhibited blue-shifted absorption at 416 and 422, respectively; however, despite of resemble spectral properties, o- and p-nitrophenyl gave second best and the worst conversion efficiencies of 4.05 and 2.51%, respectively. By combination with computational chemistry, it was indicated that the configuration of the EWG and distance between TiO2 surface and the EWG dominated electron injection efficiency. (C) 2012 The Japan Society of Applied Physics
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