4.3 Article

Enhanced Piezoelectric Constant of (1-x)BiFeO3-xBiCoO3 Thin Films Grown on LaAlO3 Substrate

Journal

JAPANESE JOURNAL OF APPLIED PHYSICS
Volume 50, Issue 3, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1143/JJAP.50.031505

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [19GS0207, 19052008, 22244044]
  2. Grants-in-Aid for Scientific Research [19052008, 22244044] Funding Source: KAKEN

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Thin films of a rhombohedral-tetragonal solid solution (1 - x)BiFeO3-xBiCoO(3) with x = 0-0.30 were prepared by chemical solution deposition on LaAlO3(001) and (La-0.5,Sr-0.5)CoO3(001)/LaAlO3(001) substrates. A BiCoO3-type tetragonal structure with a large c/a of 1.23 was grown adjacent to the substrate whereas a BiFeO3-type rhombohedral one was grown on the tetragonal phase. Co substitution in the rhombohedral phase led to enhancement of piezoelectric constant and d(33) reached 100 pm/V, almost double that of BiFeO3. (C) 2011 The Japan Society of Applied Physics

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