4.3 Article

Quantum Control Landscape for a Λ-atom in the Vicinity of Second-Order Traps

Journal

ISRAEL JOURNAL OF CHEMISTRY
Volume 52, Issue 5, Pages 467-472

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201100165

Keywords

femtochemistry; laser chemistry; quantum control; photochemistry; photophysics

Funding

  1. European Community
  2. Minerva Foundation

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We show that the second-order traps in the control landscape for a three-level ?-system found in our previous work (Phys. Rev. Lett. 2011, 106, 120402) are not local maxima: there exist directions in the space of controls in which the objective grows. The growth of the objective is slow at best 4th order for weak variations of the control. This implies that simple gradient methods would be problematic in the vicinity of second-order traps, where more sophisticated algorithms that exploit the higher order derivative information are necessary to climb up the control landscape efficiently. The theory is supported by a numerical investigation of the landscape in the vicinity of the e(t)=0 second-order trap, performed using the GRAPE and BFGS algorithms.

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