4.5 Article

Reduction mechanisms of vanadium-titanomagnetite-non-coking coal mixed pellet

Journal

IRONMAKING & STEELMAKING
Volume 38, Issue 1, Pages 59-64

Publisher

MANEY PUBLISHING
DOI: 10.1179/030192310X12816231892549

Keywords

Vanadium-titanomagnetite-non-coking mixed pellet; Non-isothermal reduction; Reduction degree; Reduction mechanism

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Experiments were carried out by testing the specimens of separate layers of iron and coal and single pellets thermogravimetrically in a nitrogen atmosphere to study the non-isothermal reduction mechanisms of vanadium-titanomagnetite-non-coking coal mixed pellets. The degree of reduction was measured by the weight loss. The E values of the pellet reduction were calculated based on the mass action law. It was found that with increasing temperature the reduction processes may be divided into four stages: reduction via CO and H(2) from volatiles at 400-650 degrees C, reduction via H(2) and C generated by cracking of hydrocarbon at 650-850 degrees C, direct reduction of carbon via gaseous intermediates at 850-1050 degrees C and direct reduction of carbon above 1050 degrees C.

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