4.5 Article

A low-temperature electrolyte for lithium-ion batteries

Journal

IONICS
Volume 21, Issue 4, Pages 901-907

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11581-014-1275-0

Keywords

Lithium-ion batteries; Low temperature; Electrolyte; Mixture salt; Electrochemical performance

Funding

  1. Science and Technology Planning Project of Gansu Province [1310RJZA043, 1308RJZA259]
  2. Natural Science Foundation of China [21406100]
  3. Science and Technology Support Project of Gansu Province [144GKCB029]
  4. Branchy Tamarisk Development Program for Young Teachers of Lanzhou University of Technology [Q201105]

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In this paper, the electrochemical performance of a new low-temperature electrolyte, 0.9 mol L-1 lithium oxalyldifluoroborate (LiODFB)/LiBF4 (5.365:1, by mass) mixed salts in the ethylene carbonate (EC)/dimethyl sulfite (DMS)/ethyl methyl carbonate (EMC) mixed solvent (1:1:3, by volume, the same below), is studied to seek the promising candidate for advanced low-temperature lithium-ion batteries (LIBs). The results show that LIBs using this new electrolyte can be operable well at temperature below -20 A degrees C. This is useful to expand the application range of LIBs, especially at specific low-temperature environments, such as military and aerospace applications.

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