Journal
MOLECULAR PHYSICS
Volume 113, Issue 17-18, Pages 2523-2530Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00268976.2015.1022609
Keywords
dense fluids; plastic crystals; colloidal dumbbells; anisotropic colloids; linear response dynamics; Brownian dynamics simulation
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We investigate the structure and equilibrium linear-response dynamics of suspensions of hard colloidal dumbbells using Brownian dynamics computer simulations. The focus lies on the dense fluid and plastic crystal states of the colloids with investigated aspect (elongation-to-diameter) ratios varying from the hard sphere limit up to 0.39, which is roughly the stability limit of the plastic crystal phase. We find expected structural changes with larger elongation with respect to the hard sphere reference case and very localised orientational correlations, typically just involving next-neighbour couplings. These relatively weak correlations are also reflected in only minor effects on the translational and rotational diffusion coefficients for most of the investigated elongations. However, the linear response shear viscosity exhibits a dramatic increase at high packing fractions (phi 0.5) beyond a critical anisotropy factor of about L* similar or equal to 0.15 which is surprising in view of the relatively weak changes found before on the level of colloidal self-dynamics. We suspect that even for the small investigated anisotropies, newly occurring, collective rotational-translational couplings must be made responsible for the slow time scales appearing in the plastic crystal.
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