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Rheo-chemistry in Reactive Processing of Polyolefin

Journal

INTERNATIONAL POLYMER PROCESSING
Volume 27, Issue 3, Pages 286-298

Publisher

CARL HANSER VERLAG
DOI: 10.3139/217.2431

Keywords

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Funding

  1. National Natural Science Foundation of China [50930002, 21074072]
  2. National Basic Research Program of China (973 Program) [2011CB606005]
  3. Shanghai Leading Academic Discipline Project [B202]
  4. SMC project of Shanghai Jiao Tong University

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A brief review of reactive processing of polyolefins, which are the most widely used polymers today, is given in this paper from the role of flow field in processing and the characterization of the modified chain topologies. The materials are mainly focused on polyethylene (PE), polypropylene (PP) and polyolefin elastomer (POE) here. Aspects of reactions, coupling/crosslinking and scission are discussed both in terms of the mechanism and kinetics under different flow conditions.

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